Federico Carò
The Metropolitan Museum of Art, Scientific Research, Department Member
- Archaeology, Earth Sciences, Landscape Archaeology, Scientific Research, Greek Archaeology, Mediterranean archaeology, and 29 moreArchaeological Science, Survey Methodology, Roman Pottery, Archaeological Chemistry, Archaeological Geophysics, Archaeological Stratigraphy, Marble Provenance, Ceramic Petrography, Mineral Prospecting/Mineral Exploration/Field Geology/Ore mineralogy/Petrography/Ore Deposits Modeling, Applied petrography for cultural heritage, portable XRF (PXRF) in Archaeology and Museum Science, X-Ray Fluorescence (XRF) Spectroscopy, Scanning Electron Microscopy, X-ray Diffraction, Materials Characterization, X-ray diffraction and Rietveld Method applied areas of physics, chemistry, geology, medical and engineering and materials science., Roman Art, Classical Archaeology, Materials Science, Archaeometry, Metal Threads in Southeast Asian Textiles, Khmer art and architecture, Khmer Studies, Ancient Glass, Analysis of Pigments on Ancient Artifacts, Archaeometallurgy, Archaeology and Art History, History of Sculpture, Gypsum, and Mineral Raw Materialsedit
The nature of ground preparations is of critical interest to those engaging in the study of historical painting techniques , as certain materials can be identified with specific regions and school of painting. This is the case of a... more
The nature of ground preparations is of critical interest to those engaging in the study of historical painting techniques , as certain materials can be identified with specific regions and school of painting. This is the case of a particular ash-based, calcite-rich material obtained as a byproduct of lye production, recently identified for the first time in ground preparations by means of chemical analysis, and which is considered specific to Baroque artists of Spanish school. Because of limitations in the size of the samples that can be removed from works of art, and because of the intrinsic variability of ash composition, chemical analysis alone may not be representative of the whole ash-containing layer, thus limiting the identification of this material. By comparing the morphology, texture and composition of calcite pseudomorphs in laboratory ash to the ground preparations in three Baroque paintings, we provide additional, unequivocal tools to identify calcite particles from ashes in paint cross sections. The results demonstrate that the chemical composition of the ash can vary, but that the morphology and size of the calcite pseudomorph crystals abundantly present in the recycled ash applied to the canvas supports are consistent and extremely characteristic. The unique polygonal shapes and skeletal morphology of the pseudomorphs and their abundance make them ideal markers to recognize ash in paintings' ground layers, even when very limited amounts of sample are available. The study shows also that the practice of using recycled ash in the preparation of ground layers occurred outside Spain, by artists with direct or indirect Spanish lineage.
Vincent van Gogh's still lifes Irises and Roses were investigated to shed light onto the degree to which the paintings had changed, both individually and in relation to each other since they were painted, particularly in regard to the... more
Vincent van Gogh's still lifes Irises and Roses were investigated to shed light onto the degree to which the paintings had changed, both individually and in relation to each other since they were painted, particularly in regard to the fading of the red lakes. Non-invasive techniques, including macroscopic X-ray fluorescence mapping, reflectance imaging spectroscopy, and X-radiography, were combined with microanalytical techniques in a select number of samples. The in-depth microchemical analysis was necessary to overcome the complications that arise when evaluating by non-invasive methods alone the compositions of passages with complex layering and mixing of paints. The results obtained by these two approaches were complemented by color measurements performed on paint cross-sections and on protected edges, and with historical information provided by the artist's own descriptions, early reviews and reproductions, and the data was used to carry out digital color simulations that provided, to a certain extent, a visualization of how the paintings may have originally appeared.
Research Interests:
Research Interests:
Research Interests:
Under Jayavarman VII (1182/83-ca.1218 CE) the Khmer empire reached its apex, leaving a heritage of major construction works and unique artistic production. The stone materials of several sculptures produced under his reign were... more
Under Jayavarman VII (1182/83-ca.1218 CE) the Khmer empire reached its apex, leaving a heritage of major construction works and unique artistic production. The stone materials of several sculptures produced under his reign were characterized and compared to possible geological sources in northern and eastern Cambodia. The data suggest that a specific type of sandstone, rich in volcanic detritus, was deliberately selected and quarried from a Triassic sedimentary sequence exposed far from Angkor, the main political and economic center at that time.
