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Federico  Carò
  • Brooklyn, New York, United States
Scholarship has focused on the Gupta age (ca. 320–550) as the quintessential expression of classical Indian art, and on the key role of metal icons in the dissemination and development of Buddhist and Hindu practice during that period and... more
Scholarship has focused on the Gupta age (ca. 320–550) as the quintessential expression of classical Indian art, and on the key role of metal icons in the dissemination and development of Buddhist and Hindu practice during that period and its aftermath into the eighth century. In fact, although well attested in contemporary texts, few bronze figures, and none in gold or silver, survived the decline of Buddhism and the destruction of monasteries during the Muslim invasions, and for those still extant, little attention has been devoted to their manufacture. Close examination of a group of hollow-cast bronze Gupta-style Buddha images from North India has revealed a unique technological style developed to meet the particular challenges of producing three-dimensional, but relatively shallow, figures with expansive garments. Unlike most figural metal statuary, the Gupta-style images were cast in a horizontal orientation, with internal gates that directed the molten metal sideways into the billowing draperies. These and other conclusions regarding their manufacture are based on visual examination, computed radiography, volumetric X-ray imaging, and X-ray fluorescence spot and line scans analyses. The spread of this technology to South India and Southeast Asia parallels the wide ranging propogation of the Gupta style, but the specialized knowledge necessary to produce such images points to the movement of experienced craftsmen between these regions and the Gupta heartland.
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Non-invasive methods including micro-Raman spectroscopy (μ-Raman), micro X-ray fluorescence (μ-XRF), fibre optics reflectance spectroscopy (FORS) and environmental scanning electron microscopy (ESEM) were used to study thirty-five ceramic... more
Non-invasive methods including micro-Raman spectroscopy (μ-Raman), micro X-ray fluorescence (μ-XRF), fibre optics reflectance spectroscopy (FORS) and environmental scanning electron microscopy (ESEM) were used to study thirty-five ceramic shards from Afrasiyab and forty-seven potshards from Nishapur. These shards are dated from the ninth to the tenth century AD and include various types of underglaze and inglaze decoration. Non-invasive scientific studies indicated that tin oxide was employed as a white opacifier in both sites while silicates including quartz, olivine, diopside and feldspar served as opacifier in Afrasiyab shards thus demonstrating a technological connection with the pre-Islamic tradition of glaze opacification. The white slip of most of the wares excavated at Nishapur contained dehydrated pyrophyllite which may be indicative of local production. Furthermore, while a dense distribution of chromite was found in the black underglaze decoration of the so-called yellow staining black ware from Nishapur, a diluted chromite probably obtained from a different source was used in the imitated lustre wares from Afrasiyab. Mixtures with different proportions of manganese oxide and black haematite were utilised as the black colouring agents. Taking all of these findings into account, it is proposed that a consistent ceramic technology and production is represented by the entire set of the shards from Afrasiyab while different materials and technologies are evinced in the Nishapur ceramics.
The nature of ground preparations is of critical interest to those engaging in the study of historical painting techniques , as certain materials can be identified with specific regions and school of painting. This is the case of a... more
The nature of ground preparations is of critical interest to those engaging in the study of historical painting techniques , as certain materials can be identified with specific regions and school of painting. This is the case of a particular ash-based, calcite-rich material obtained as a byproduct of lye production, recently identified for the first time in ground preparations by means of chemical analysis, and which is considered specific to Baroque artists of Spanish school. Because of limitations in the size of the samples that can be removed from works of art, and because of the intrinsic variability of ash composition, chemical analysis alone may not be representative of the whole ash-containing layer, thus limiting the identification of this material. By comparing the morphology, texture and composition of calcite pseudomorphs in laboratory ash to the ground preparations in three Baroque paintings, we provide additional, unequivocal tools to identify calcite particles from ashes in paint cross sections. The results demonstrate that the chemical composition of the ash can vary, but that the morphology and size of the calcite pseudomorph crystals abundantly present in the recycled ash applied to the canvas supports are consistent and extremely characteristic. The unique polygonal shapes and skeletal morphology of the pseudomorphs and their abundance make them ideal markers to recognize ash in paintings' ground layers, even when very limited amounts of sample are available. The study shows also that the practice of using recycled ash in the preparation of ground layers occurred outside Spain, by artists with direct or indirect Spanish lineage.
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Eighteen glazed objects from Nimrud, Hasanlu and Borsippa dated to a period from the ninth to sixth century BCE were analysed by micro X-ray fluorescence (μ-XRF), X-ray diffractometry (XRD), scanning electron microscopy (SEM) coupled with... more
Eighteen glazed objects from Nimrud, Hasanlu and Borsippa dated to a period from the ninth to sixth century BCE were analysed by micro X-ray fluorescence (μ-XRF), X-ray diffractometry (XRD), scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDS) and micro-Raman spectroscopy (μ-Raman). While calcium antimonate (CaSb2O6) and lead pyroantimonate (Pb2Sb2O7) were the main white and yellow opacifiers of the glazes, respectively, white sodium antimonate (NaSbO3) was also sporadically observed in the Nimrud glazes. Copper sulphide associated with cassiterite (SnO2) was used as colouring agent – or probably as opacifier – in a green glaze from Hasanlu. Cassiterite associated with the slag of Cu-Sn copper alloys was also observed in a green glaze from Nimrud suggesting a close tie between metallurgy and glaze-making. Pyromorphite (Pb5(PO4)3Cl) and arsenian pyromorphite were observed in spherical forms embedded in the yellow glazes of Nimrud and Borsippa.
Vincent van Gogh's still lifes Irises and Roses were investigated to shed light onto the degree to which the paintings had changed, both individually and in relation to each other since they were painted, particularly in regard to the... more
Vincent van Gogh's still lifes Irises and Roses were investigated to shed light onto the degree to which the paintings had changed, both individually and in relation to each other since they were painted, particularly in regard to the fading of the red lakes. Non-invasive techniques, including macroscopic X-ray fluorescence mapping, reflectance imaging spectroscopy, and X-radiography, were combined with microanalytical techniques in a select number of samples. The in-depth microchemical analysis was necessary to overcome the complications that arise when evaluating by non-invasive methods alone the compositions of passages with complex layering and mixing of paints. The results obtained by these two approaches were complemented by color measurements performed on paint cross-sections and on protected edges, and with historical information provided by the artist's own descriptions, early reviews and reproductions, and the data was used to carry out digital color simulations that provided, to a certain extent, a visualization of how the paintings may have originally appeared.
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Between the 9th and 15th centuries CE the builders and artisans of Angkor and its territories furnished their landscapes with thousands of temples and tens of thousands of sacred sculptures, yet the operational behaviour of these craft... more
Between the 9th and 15th centuries CE the builders and artisans of Angkor and its territories furnished their landscapes with thousands of temples and tens of thousands of sacred sculptures, yet the operational behaviour of these craft specialists is little known. This article presents the results of excavations and materials analysis from a centre of sandstone production for the classic period Angkorian city of Hariharālaya and appraises the procurement of raw materials, manufacturing methods, and sites of production for the makers of temples and sculptures. A production site associated with the temple of Bakong was identified by surface remains of sandstone debitage and unfinished sculptures. Excavation revealed a 9th-century building associated with large-scale sandstone waste deposits and another phase of sculpture production in the 12th and 13th centuries. A study of sandstone characterisation was applied to in situ production waste, unfinished sculptures from the workshop, and on completed works. Comparison of samples from the workshop and associated temples with sculptures from Cambodian and international collections suggest the site was likely used as a dump for construction of nearby temples and later to produce images of the gods destined for veneration. Moreover, the workshop was part of a network of craft specialists who sourced many thousands of tons of specific sandstone across the Angkorian landscape.

Polkinghorne, M., Douglas, J..and Carò, F., 2015. “Carving at the Capital: A stone workshop at Hariharālaya, Angkor", in Bulletin l’École Française d’Extrême-Orient (BEFEO), vol. 101: 55 - 90.
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Pigments appearing on ninth–twelfth-century AD-carved stucco, wall painting, and terracotta friezes excavated at Nishapur in north-eastern Iran were investigated by optical reflectance spectroscopy, micro X-ray fluorescence spectrometry... more
Pigments appearing on ninth–twelfth-century AD-carved stucco, wall painting, and terracotta friezes excavated at Nishapur in north-eastern Iran were investigated by optical reflectance spectroscopy, micro X-ray fluorescence spectrometry (μ-XRF), X-ray diffractometry (XRD), micro-Raman spectroscopy (μ-Raman), and scanning electron microscopy (SEM). Many of the pigments identified including vermilion, red lead, hematite, limonite, carbon black, atacamite, calcite, and gypsum have been identified in previous studies of pigments used in later Islamic periods. However, a series of unusual pigments such as wulfenite, pyromorphite, phoenicochroite, and jarosite were also found in the present study. The association of kaolinite and alunite with limonite and other Fe-bearing yellow pigments points to a local provenance for these pigments. In addition, the presence of orpiment in the vermilion may be indicative that the vermilion was artificially manufactured. These findings suggest that pigment use and manufacturing during the ninth to eleventh centuries in Nishapur was still in a trial-and-error stage and the palette known from the twelfth century onwards had not yet been systematized.
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Under Jayavarman VII (1182/83-ca.1218 CE) the Khmer empire reached its apex, leaving a heritage of major construction works and unique artistic production. The stone materials of several sculptures produced under his reign were... more
Under Jayavarman VII (1182/83-ca.1218 CE) the Khmer empire reached its apex, leaving a heritage of major construction works and unique artistic production. The stone materials of several sculptures produced under his reign were characterized and compared to possible geological sources in northern and eastern Cambodia. The data suggest that a specific type of sandstone, rich in volcanic detritus, was deliberately selected and quarried from a Triassic sedimentary sequence exposed far from Angkor, the main political and economic center at that time.
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